Cleveland Ironstone Formation
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The Cleveland Ironstone Formation is a sequence of marine
ironstone Ironstone is a sedimentary rock, either deposited directly as a ferruginous sediment or created by chemical replacement, that contains a substantial proportion of an iron ore compound from which iron (Fe) can be smelted commercially. Not to be con ...
seams interbedded with
shale Shale is a fine-grained, clastic sedimentary rock formed from mud that is a mix of flakes of clay minerals (hydrous aluminium phyllosilicates, e.g. kaolin, Al2 Si2 O5( OH)4) and tiny fragments (silt-sized particles) of other minerals, especial ...
and
siltstone Siltstone, also known as aleurolite, is a clastic sedimentary rock that is composed mostly of silt. It is a form of mudrock with a low clay mineral content, which can be distinguished from shale by its lack of fissility.Blatt ''et al.'' 1980, p ...
units which collectively form a part of the
Lower Jurassic The Early Jurassic Epoch (in chronostratigraphy corresponding to the Lower Jurassic Series) is the earliest of three epochs of the Jurassic Period. The Early Jurassic starts immediately after the Triassic-Jurassic extinction event, 201.3 Ma&nb ...
System of rocks underlying
Cleveland Cleveland ( ), officially the City of Cleveland, is a city in the U.S. state of Ohio and the county seat of Cuyahoga County. Located in the northeastern part of the state, it is situated along the southern shore of Lake Erie, across the U.S. ...
in
North Yorkshire North Yorkshire is the largest ceremonial counties of England, ceremonial county (lieutenancy area) in England, covering an area of . Around 40% of the county is covered by National parks of the United Kingdom, national parks, including most of ...
. Exploitation of the ironstone seams became a major driving force behind the industrialisation of the
Teesside Teesside () is a built-up area around the River Tees in the north of England, split between County Durham and North Yorkshire. The name was initially used as a county borough in the North Riding of Yorkshire. Historically a hub for heavy manu ...
district during the mid- to late-1800s. Based on the stratigraphy of the formation, the Cleveland Ironstone was found to belong within the Upper
Pliensbachian The Pliensbachian is an age of the geologic timescale and stage in the stratigraphic column. It is part of the Early or Lower Jurassic Epoch or Series and spans the time between 190.8 ± 1.5 Ma and 182.7 ± 1.5 Ma (million years ago). The Plien ...
(Domerian) universal stage.
Ironstone Ironstone is a sedimentary rock, either deposited directly as a ferruginous sediment or created by chemical replacement, that contains a substantial proportion of an iron ore compound from which iron (Fe) can be smelted commercially. Not to be con ...
seams and accompanying
shale Shale is a fine-grained, clastic sedimentary rock formed from mud that is a mix of flakes of clay minerals (hydrous aluminium phyllosilicates, e.g. kaolin, Al2 Si2 O5( OH)4) and tiny fragments (silt-sized particles) of other minerals, especial ...
s may be highly fossiliferous with remains so abundant in parts as to form well-developed shell-beds. Analysis reveals a wealth of shallow-water marine species, some in life position, along with
trace fossil A trace fossil, also known as an ichnofossil (; from el, ἴχνος ''ikhnos'' "trace, track"), is a fossil record of biological activity but not the preserved remains of the plant or animal itself. Trace fossils contrast with body fossils, ...
s including '' Rhizocorallium'' burrows well exposed at Old Nab, east of Staithes.


Stratigraphy

Formerly classified as part of the Middle Lias, these strata were deposited over a period of about 2 million years, as soft sediment on the floor of a shallow arm of the ancient
Tethys Ocean The Tethys Ocean ( el, Τηθύς ''Tēthús''), also called the Tethys Sea or the Neo-Tethys, was a prehistoric ocean that covered most of the Earth during much of the Mesozoic Era and early Cenozoic Era, located between the ancient continents ...
, between c.185 million and 183 million years before present. The formation lies conformably on the prolifically-fossiliferous shallow marine sandstone, siltstone and mudrock of the Staithes Formation. There are six named ironstone seams which are, in order of deposition, the Osmotherley,'' Avicula'', Raisdale, Two-foot, ''Pecten'' and Main Seams. At its type locality, on the coast around
Staithes Staithes is a seaside village in the borough of Scarborough in North Yorkshire, England. Easington and Roxby Becks, two brooks that run into Staithes Beck, form the border between the Borough of Scarborough and Redcar and Cleveland. The area l ...
, North Yorkshire, the formation attains a thickness of 25.3 metres and comprises five 'coarsening-upward' cycles of marine shale and siltstone each capped by a seam of ironstone of varying thickness, composition and iron-content. The shales and siltstones are grey in colour, and exhibit occasional bands of calcareous or sideritic nodules, shell-beds and cross-bedding. The uppermost reaches of some of the shale units may be laminated and have been dubbed tempestites. Immediately beneath the Raisdale Seam at Staithes can be seen laminated beds with basal gutters up to wide and long which were scoured out during high energy storm events. The gutters have been subsequently infilled with fine sand and silt which shows signs of pyritisation. These features tend to be oriented in an east-west direction and are fairly persistent laterally, occurring almost to the south-east at
Hawsker Hawsker is the name for the combined villages of High and Low Hawsker that straddle the A171 road south east of Whitby, in North Yorkshire, England. History The name Hawsker derives from Old Norse and means Haukr's enclosure. The settlement ...
Bottoms. Definitive zonal work has been carried out on the coast by Howarth (1953), Howard (1985) and extended inland by Chowns (1968). Their efforts reveal that these strata span two faunal zones prompting subdivision into corresponding informal units. The lowest are predominantly shaley and include the Osmotherly, ''Avicula'', Raisdale and Two-foot Seams, the best-developed being the ''Avicula'' Seam attaining c.0.5 metre at Jet Wyke. They reside within the upper part of the ''Amaltheus margaritatus'' faunal zone and are collectively referred to as the Penny Nab Member, after a headland c.150 metres east of Staithes Harbour. An
unconformity An unconformity is a buried erosional or non-depositional surface separating two rock masses or strata of different ages, indicating that sediment deposition was not continuous. In general, the older layer was exposed to erosion for an interval o ...
marks transition to the overlying '' Pleuroceras spinatum'' zone which covers the more ferruginous upper 6 metres of the formation. It is referred to as the Kettleness Member, and includes the ''Pecten'' and Main Seams, the latter c.1.8 metres thick and split into a 0.7 metre ''Top Block'' and 0.8 metre ''Bottom Block'' by 0.3 metre of medial shale at Old Nab. The most important seams, from an economic perspective, are the Main and ''Pecten'' Seams which attain their greatest development along the northern edge of the ore-field, near Eston. There the Main Seam, 3.66 metres thick, rests directly on the ''Pecten'' Seam (1.23 metres) which includes an impressive shell-bed. The seams are relatively persistent in an east-west direction, but shale-partings intervene and thicken to the south at the expense of the ironstone. In East Cleveland the strata pass through a structural syncline known as the Skelton Syncline where the Main Seam descends to around below sea level around
North Skelton North Skelton is a village in the unitary authority of Redcar and Cleveland and the ceremonial county of North Yorkshire, England. The village is actually east of Skelton-in-Cleveland and just south of the A174 road between Thornaby and Whitby ...
. The whole formation thins and becomes less-ferruginous to the south as the Main Seam, itself much diminished, oversteps each of the underlying seams one-by-one. Strata of this age are completely absent at the southerly limit of the Yorkshire Basin around
Market Weighton Market Weighton ( ) is a town and civil parish in the East Riding of Yorkshire, England. It is one of the main market towns in the East Yorkshire Wolds and lies midway between Hull and York, about from either one. According to the 2011 UK cen ...
.


Lithology

On average the Cleveland Ironstone Formation comprises around 70% shale and 30% ironstone though the latter occurs in the form of the six named seams of variable thickness. The ironstone is classed as being low-grade with an iron-content of up to 33%, and is deemed economically viable only above ~27%. The primary iron-bearing minerals are the iron carbonate siderite (FeCO3) and berthierine (formerly known as
chamosite Chamosite is the Fe2+end member of the chlorite group. A hydrous aluminium silicate of iron, which is produced in an environment of low to moderate grade of metamorphosed iron deposits, as gray or black crystals in oolitic iron ore. Like other c ...
,(). Ancillary components include
calcite Calcite is a Carbonate minerals, carbonate mineral and the most stable Polymorphism (materials science), polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on ...
(as MgCO3 and MnCO3),
pyrite The mineral pyrite (), or iron pyrite, also known as fool's gold, is an iron sulfide with the chemical formula Iron, FeSulfur, S2 (iron (II) disulfide). Pyrite is the most abundant sulfide mineral. Pyrite's metallic Luster (mineralogy), lust ...
(FeS2), collophanite (Ca3P2O8 H2O ),
silica Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is one ...
(Si), clay minerals and derivatives such as
octahedrite Octahedrites are the most common structural class of iron meteorites. The structures occur because the meteoric iron has a certain nickel concentration that leads to the exsolution of kamacite out of taenite while cooling. Structure Octahedri ...
(
brookite Brookite is the orthorhombic variant of titanium dioxide (TiO2), which occurs in four known natural polymorphic forms (minerals with the same composition but different structure). The other three of these forms are akaogiite (monoclinic), anatas ...
) (TiO2), and
dickite Dickite () is a phyllosilicate clay mineral named after the metallurgical chemist Allan Brugh Dick, who first described it. It is chemically composed of 20.90% aluminium, 21.76% silicon, 1.56% hydrogen and 55.78% oxygen. It has the same comp ...
(Al2Si2O5(OH)4). The seams are often oolitic, especially in the north of the district, but vary in constitution across the ore-field. The
ooids Ooids are small (commonly ≤2 mm in diameter), spheroidal, "coated" (layered) sedimentary grains, usually composed of calcium carbonate, but sometimes made up of iron- or phosphate-based minerals. Ooids usually form on the sea floor, m ...
(on average) comprise ~33% siderite, ~33% berthierine, and a similar proportion of ancillary minerals and demonstrate deformation whilst the sediment was still plastic. The origins of the ironstone seams have been the subject of much argument and counter-argument since their large scale exploitation commenced in the mid-1800s. The most widely accepted explanation emerged in the 1920s following analysis by Hallimond (1925). This suggests that the concentration of dissolved iron within the surrounding sea-water remained approximately the same during deposition of both shale and ironstone. The physical differences between the two arises as the result of variations in sediment influx. Rapid rates of sediment input caused deposition of the
shale Shale is a fine-grained, clastic sedimentary rock formed from mud that is a mix of flakes of clay minerals (hydrous aluminium phyllosilicates, e.g. kaolin, Al2 Si2 O5( OH)4) and tiny fragments (silt-sized particles) of other minerals, especial ...
s, whereas a diminished rate of input enabled the same amount of iron to be concentrated within a lower sediment load thereby producing the ironstone seams. Evidence of
bivalves Bivalvia (), in previous centuries referred to as the Lamellibranchiata and Pelecypoda, is a class of marine and freshwater molluscs that have laterally compressed bodies enclosed by a shell consisting of two hinged parts. As a group, bival ...
in life position, '' Rhizocorallium'' trace fossils,
cross-bedding In geology, cross-bedding, also known as cross-stratification, is layering within a stratum and at an angle to the main bedding plane. The sedimentary structures which result are roughly horizontal units composed of inclined layers. The origina ...
, episodes of non-deposition and (not least) the oolitic texture all indicate that the ironstones were laid down in shallow water. Fossils are ubiquitous, especially within the ironstone seams, to the extent that the '' Avicula'' and '' Pecten'' seams are named after their most abundant faunal inclusions. NOTE: The only surviving extensive outcrop of the Main Seam occurs in woodland north of Skelton (close to NZ 6554 1997) at around 50m O.D above Skelton Beck achieving a thickness of around 2.4m (8 feet). It is underlain by the Black Hard, and three beds making up the ''Pecten'' Seam.


Economic history

Economically, the Cleveland Ironstone proved to be a crucial catalyst with the power to reinvigorate the flagging commercial fortunes of the River Tees and surrounding district. The occurrence of ironstone in Cleveland has been known about for many centuries with evidence of small scale working predating the occupation of
Roman Britain Roman Britain was the period in classical antiquity when large parts of the island of Great Britain were under occupation by the Roman Empire. The occupation lasted from AD 43 to AD 410. During that time, the territory conquered was ...
. Despite much early attention, the true extent of the Cleveland ore-field remained a mystery until the late-1840s, when ironmaster John Vaughan (1799–1868) and mining engineer
John Marley John Marley (born Mortimer Marlieb, October 17, 1907 – May 22, 1984) was an American actor who was known for his role as Phil Cavalleri in '' Love Story'' and as Jack Woltz—the defiant film mogul who awakens to find the severed head ...
(1823–1891), both of the
Bolckow Vaughan Bolckow, Vaughan & Co., Ltd was an English steelmaking, ironmaking and mining company founded in 1864, based on the partnership since 1840 of its two founders, Henry Bolckow and John Vaughan (ironmaster), John Vaughan. The firm drove the dramat ...
company, traced seams of ironstone along the coast between Staithes and their northerly outcrop on the escarpment of the Eston Hills overlooking the River Tees. Vaughan and Marley's evidence of a large scale body of workable iron ore in close proximity to both coal and limestone from County Durham, together with the district's developing communications network by rail and sea, proved a heady concoction. Combine with this an insatiable appetite for manufactured goods driven by the
Industrial Revolution The Industrial Revolution was the transition to new manufacturing processes in Great Britain, continental Europe, and the United States, that occurred during the period from around 1760 to about 1820–1840. This transition included going f ...
and a cohort of shrewd opportunist business speculators, and it may come as no surprise that
Middlesbrough Middlesbrough ( ) is a town on the southern bank of the River Tees in North Yorkshire, England. It is near the North York Moors national park. It is the namesake and main town of its local borough council area. Until the early 1800s, the a ...
developed rapidly, led by Bolckow Vaughan, which mined and refined iron, and manufactured goods from it. The town grew from a mere idea in the late-1820s, to become the commercial centre of one of the world's greatest iron and steel producing regions in little over two generations. By 1881, the year of Middlesbrough's Golden Jubilee, output of ironstone drawn from the Cleveland ore-field exceeded 6,000,000 tons (6,096,360 tonnes).


See also

*
Ironstone mining in Cleveland and North Yorkshire Ironstone mining in Cleveland and North Yorkshire occurred on a sizeable scale from the 1830s to the 1960s in present day eastern parts of North Yorkshire but has been recorded as far back as Roman times in mostly a small-scale and intended for ...


References

{{reflist, 33em Geologic formations of the United Kingdom Geology of North Yorkshire Stratigraphy of the United Kingdom Mining in North Yorkshire Pliensbachian Stage Jurassic System of Europe Jurassic England